Synthesis and characterization of a nickel(II) complex with a tridentate hybrid ligand containing phosphorus and sulfur

被引：8

作者：

Cheng, CR ^{[1
]}

Leung, PH ^{[1
]}

Mok, KF ^{[1
]}

机构：

[1] NATL UNIV SINGAPORE, DEPT CHEM, SINGAPORE 117548, SINGAPORE

来源：

POLYHEDRON | 1996年 / 15卷 / 08期

关键词：

D O I：

10.1016/0277-5387(95)00420-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel complex [Ni(pps)Cl-2]. CH2Cl2 (pps = bis(3-(diphenylphosphino)propyl)sulphide) has been synthesized as brown prisms and characterized by X-ray crystallography. The coordination sphere around NI(II) is distorted square-pyramidal with a chloro ligand coordinated in the fifth position. A similar structure is assigned to the complex in solution.

引用

页码：1401 / 1404

页数：4

共 19 条

[1] SYNTHESIS AND EVALUATION OF THE BONDING PROPERTIES OF 2,5-BIS(2-(DIPHENYLPHOSPHINO)ETHYL)THIOPHENE - A NEW POTENTIALLY TRIDENTATE LIGAND [J].

ALVAREZ, M ;

LUGAN, N ;

MATHIEU, R .

INORGANIC CHEMISTRY, 1993, 32 (25) :5652-5657

[2] COORDINATION CHEMISTRY AND CATALYSIS WITH HEMILABILE OXYGEN PHOSPHORUS LIGANDS [J].

BADER, A ;

LINDNER, E .

COORDINATION CHEMISTRY REVIEWS, 1991, 108 (01) :27-110

[3] STRUCTURES OF COMPLEXES BETWEEN METAL-HALIDES AND PHOSPHINOTHIOETHERS OR RELATED LIGANDS .14. [BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE]IODONICKEL(II) TETRAPHENYLBORATE, C34H33INIP3+.C24H20B-, AND [BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE]CHLORONICKEL(II) TETRAPHENYLBORATE, C34H33CLNIP3+.C24H20B- [J].

BERTINSSON, GI .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (MAY) :563-567

[4] DIBROMOTRIS(TRIMETHYLPHOSPHINE)NICKEL(2) [J].

CHASTAIN, BB ;

MEEK, DW ;

BILLIG, E ;

HIX, JE ;

GRAY, HB .

INORGANIC CHEMISTRY, 1968, 7 (11) :2412-&

[5]

Cotton F.A., 1992, Prog. Inorg. Chem., P179

[6] NICKEL- UND PALLADIUMKOMPLEXE MIT PHOSPHINOTHIOATHERN [J].

DEGISCHER, G ;

SCHWARZENBACH, G .

HELVETICA CHIMICA ACTA, 1966, 49 (06) :1927-+

[7]

FULINA C, 1968, COORDIN CHEM REV, V3, P141

[8]

Gee W., 1967, INORG SYN, V9, P19

[9] CONFORMATIONAL-ANALYSIS OF COORDINATION-COMPOUNDS .5. 6-MEMBERED DIAMINE CHELATE RINGS [J].

GOLLOGLY, JR ;

HAWKINS, CJ .

INORGANIC CHEMISTRY, 1972, 11 (01) :156-&

[10]

Greenwood N.N., 1984, CHEM ELEMENTS

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