Unusual crystalline heterobimetallic trinuclear β-diketiminates [Yb{L(μ-Li(thf)}2] and [Yb{L′(μ-Li(thf)}2]• thf [L, L′ = {N(SiMe3)C(R)}2CH, R = Ph, C6H4Ph-4]

被引：43

作者：

Avent, AG ^{[1
]}

Khvostov, AV ^{[1
]}

Hitchcock, PB ^{[1
]}

Lappert, MF ^{[1
]}

机构：

[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 13期

关键词：

D O I：

10.1039/b203321f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

YbCl3 with successively 2KL or 2KL and then > 2Li in thf yields crystalline [Yb{L(mu-Li( thf)}(2)] 1 or [Yb{L'(mu-Li( thf)}(2)]. thf 2, characterised by X-ray, multinuclear NMR spectral and VT magnetic susceptibility data; 1 and 2 are best formulated as Yb( II) complexes having dianionic L2- or L'(2-) ligands, L or L' = {N(SiMe3)C(R)}(2)CH (R = Ph or C6H4Ph-4).

引用

页码：1410 / 1411

页数：2

共 15 条

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