Photoinduced anisotropic conversion of bonding and lone-pair electrons in As2S3 glass

被引:36
作者
Kolobov, AV [1 ]
Lyubin, V [1 ]
Yasuda, T [1 ]
Tanaka, K [1 ]
机构
[1] BEN GURION UNIV NEGEV, DEPT PHYS, IL-84105 BEER SHEVA, ISRAEL
关键词
D O I
10.1103/PhysRevB.55.23
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present the results of a study of photoinduced anisotropy in a model chalcogenide glass As2S3 in a wide spectral range using reflectance-difference spectroscopy. We have found that the anisotropy is induced at energies much exceeding the energy of the inducing photons and that the sign of the photoinduced anisotropy is opposite at smaller and higher energies. To explain the results, we suggest a model considering redistribution between bonding and lone-pair electrons.
引用
收藏
页码:23 / 25
页数:3
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