New single source route to the molybdenum nitride Mo2N

被引:94
作者
Afanasiev, P [1 ]
机构
[1] Inst Rech Catalyse, F-69626 Villeurbanne, France
关键词
D O I
10.1021/ic025564d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dispersed Mo2N with lamellar morphology and high specific surface area was obtained from the decomposition of the (HMT)(2)(NH4)(4)-Mo7O24 salt (HMT = hexamethylentertramine) in the temperature range 550-800 degreesC. During the thermal decomposition, reduction of Mo species by carbon from the HMT ligand occurs, with release of CO gas.
引用
收藏
页码:5317 / 5319
页数:3
相关论文
共 19 条
  • [1] New synthetic routes to transition metal ternary nitrides and sulfides
    Barker, MG
    Francesconi, MG
    O'Meara, PM
    Baker, CF
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 317 : 186 - 189
  • [2] Synthesis of cubic boron nitride at low-temperature and low-pressure conditions
    Hao, XP
    Cui, DL
    Shi, GX
    Yin, YQ
    Xu, XG
    Wang, JY
    Jiang, MH
    Xu, XW
    Li, YP
    Sun, BQ
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (08) : 2457 - 2459
  • [3] PREPARATION OF HIGH-SURFACE-AREA TRANSITION-METAL NITRIDES - MO2N AND MON
    JAGGERS, CH
    MICHAELS, JN
    STACY, AM
    [J]. CHEMISTRY OF MATERIALS, 1990, 2 (02) : 150 - 157
  • [4] An alternative synthesis of cyclotrigallazane, [H2GaNH2](3), a precursor to nanocrystalline, phase-inhomogeneous gallium nitride, GaN
    Janik, JF
    Wells, RL
    [J]. INORGANIC CHEMISTRY, 1997, 36 (18) : 4135 - 4137
  • [5] Ammonothermal conversion of cyclotrigallazane to GaN:: Synthesis of nanocrystalline and cubic GaN from [H2GaNH2]3
    Jegier, JA
    McKernan, S
    Purdy, AP
    Gladfelter, WL
    [J]. CHEMISTRY OF MATERIALS, 2000, 12 (04) : 1003 - 1010
  • [6] Synthesis of aluminum nitride by a modified carbothermal reduction and nitridation method using basic dicarboxylate Al(III) complexes Al(OH)(Cn+2H2nO4)•xH2O (n=3, 6, 8)
    Jung, WS
    Ahn, SK
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (01) : 79 - 85
  • [7] Crystal growth of gallium nitride in supercritical ammonia
    Ketchum, DR
    Kolis, JW
    [J]. JOURNAL OF CRYSTAL GROWTH, 2001, 222 (03) : 431 - 434
  • [8] Cobalt molybdenum bimetallic nitride catalysts for ammonia synthesis - Part 1. Preparation and characterization
    Kojima, R
    Aika, K
    [J]. APPLIED CATALYSIS A-GENERAL, 2001, 215 (1-2) : 149 - 160
  • [9] LEE JG, 1979, AM CERAM SOC BULL, V58, P869
  • [10] Hydrotreating of heavy vacuum gas oil (HVGO) on molybdenum and tungsten nitrides catalytic phases
    Melo-Banda, JA
    Domínguez, JM
    Sandoval-Robles, G
    [J]. CATALYSIS TODAY, 2001, 65 (2-4) : 279 - 284