Toward the synthesis of biologically important chlorins, isobacteriochlorins, and corrins. Cyclic enamides from acetylenic amides

被引:62
作者
Jacobi, PA
Brielmann, HL
Hauck, SI
机构
[1] Hall-Atwater Laboratories, Wesleyan University, Middletown
关键词
D O I
10.1021/jo960428+
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Cyclic enamides 1 of a type useful in the synthesis of naturally occurring chlorins, isobacteriochlorins, and corrins have been prepared by a process involving 5-exo-dig cyclization of the appropriate acetylenic amides 11. The desired cyclization is catalyzed by either n-Bu(4)NF or LiAl-(NHBn)(4).
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页码:5013 / 5023
页数:11
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