Layer-by-layer assembly and electrochemical properties of sandwiched film of manganese oxide nanosheet and carbon nanotube

被引:73
作者
Zheng, Huajun [1 ,2 ,3 ]
Tang, Fengqiu [1 ]
Jia, Yi [1 ]
Wang, Lianzhou [1 ]
Chen, Yuchun [1 ]
Lim, Melvin [1 ]
Zhang, Lei [1 ]
Lu, Gaoqing [1 ]
机构
[1] Univ Queensland, ARC Ctr Excellence Funct Nanomat, Brisbane, Qld 4072, Australia
[2] Zhejiang Univ Technol, Zhijiang Coll, Hangzhou 310024, Zhejiang, Peoples R China
[3] Zhejiang Univ Technol, State Key Lab Breeding Base Green Chem Synth Tech, Hangzhou 310014, Zhejiang, Peoples R China
基金
澳大利亚研究理事会; 浙江省自然科学基金;
关键词
EXFOLIATED MNO2 NANOSHEETS; HYDROTHERMAL SYNTHESIS; COMPOSITE ELECTRODES; ULTRATHIN FILMS; SUPERCAPACITORS; PERFORMANCE; FABRICATION; DEPOSITION;
D O I
10.1016/j.carbon.2009.02.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sandwiched film of MnO2 nanosheet (MONS) and multi-walled carbon nanotube (MWCNT) was assembled by using the layer-by-layer method, based on electrostatic interaction of positively -charged poly (diallyl dirnethyl ammonium chloride) and negatively-charged MONS and MWCNT. Ultraviolet-visible spectroscopy is used to probe the dynamic growth of multilayer film, exhibiting progressive enhancement of optical absorption due to the assembly of MONS and MWCNT. Thus, the assembled sandwiched film was characterized using scanning electron microscopy and X-ray photoelectron spectra. The multilayer film electrode presents excellent electrochemical capacitance properties, which were also highly dependent upon the deposition sequence and the order of structural components in sandwiched film. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1534 / 1542
页数:9
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