High-Tc superconductivity induced by doping rare-earth elements into CaFeAsF

被引:86
作者
Cheng, Peng [1 ]
Shen, Bing
Mu, Gang
Zhu, Xiyu
Han, Fei
Zeng, Bin
Wen, Hai-Hu
机构
[1] Chinese Acad Sci, Natl Lab Superconduct, Inst Phys, Beijing 100190, Peoples R China
关键词
D O I
10.1209/0295-5075/85/67003
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We have successfully synthesized the fluoride-arsenide compounds Ca1-xRExFeAsF (RE = Nd, Pr; x= 0, 0.6). The X-ray powder diffraction confirmed that the main phases of our samples are Ca1-xRExFeAsF with the ZrCuSiAs structure. By measuring resistivity, superconductivity was observed at 56K in Nd-doped and 52 K in Pr-doped samples with x=0.6. Bulk superconductivity was also proved by the DC magnetization measurements in both samples. Hall effect measurements revealed hole-like charge carriers in the parent compound CaFeAsF with a clear resistivity anomaly below 118 K, while the Hall coefficient RH in the normal state is negative for the superconducting samples Ca0.4Nd0.6FeAsF and Ca0.4Pr0.6FeAsF. This indicates that the rare-earth element doping introduces electrons into CaFeAsF, which induces high-temperature superconductivity. Copyright (C) EPLA, 2009
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页数:4
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