Direct Observation of Contact Ion-Pair Formation in Aqueous Solution

被引：122

作者：

Antonio, Mark R. ^{[1
]}

Nyman, May ^{[2
]}

Anderson, Travis M. ^{[2
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

[2] Sandia Natl Labs, Dept Geochem, Albuquerque, NM 87185 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 33期

关键词：

alkali metals; cluster compounds; ion pairs; polyoxometalates; small-angle X-ray scattering; X-RAY SOLUTION; SOLID-STATE; ELECTRON-TRANSFER; LINDQVIST ION; SCATTERING; COMPLEXES; HETEROPOLYNIOBATES; PRECIPITATION; ASSOCIATION; INSTRUMENT;

D O I：

10.1002/anie.200805323

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nude or neutralized? Small-angle X-ray Scattering (SAXS) measurements provide direct observation of contact ion pairing between the [Nb 6O19]8- polyoxometalate and its eight charge-balancing cesium cations in aqueous solution. The radius of gyration (Rg) for Cs8[Nb6O19] and [Nb 6O19]8- is shown. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6136 / 6140

页数：5

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