Mechanistic studies on ruthenium-catalyzed hydrogen transfer reactions

被引：85

作者：

Laxmi, YRS ^{[1
]}

Bäckvall, JE ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 07期

关键词：

D O I：

10.1039/b000530o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium-catalyzed hydrogen transfer from (S)-alpha-deuterio-alpha-phenylethanol [(S)-1] to acetophenone with catalyst 3 occurs with retention of deuterium at the alpha-carbon of the alcohol product whereas H/D scrambling occurs with catalyst 2.

引用

页码：611 / 612

页数：2

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