Understanding the relative easiness of oxidative addition of aryl and alkyl halides to palladium(0)

被引：134

作者：

Ariafard, Alireza

Lin, Zhenyang

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

[2] Hong Kong Univ Sci & Technol, Open Lab Chirotechnol, Inst Mol Technol Drug Discovery & Synth, Kowloon, Hong Kong, Peoples R China

[3] Islamic Azad Univ, Fac Sci, Dept Chem, Cent Tehran Branch, Tehran, Iran

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 16期

关键词：

D O I：

10.1021/om060236x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Density functional theory calculations were carried out to study the relative easiness of oxidative addition of aryl and alkyl halides to Pd(0). Kinetic but not thermodynamic factors were found to contribute to the better reactivity of aryl versus alkyl halides.

引用

页码：4030 / 4033

页数：4

共 51 条

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