Chemistry of strained organometallic rings:: Unusual reactivity of tin-bridged [1]ferrocenophanes with metal carbonyls

被引：13

作者：

Berenbaum, A ^{[1
]}

Jäkle, F ^{[1
]}

Lough, AJ ^{[1
]}

Manners, I ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 12期

关键词：

D O I：

10.1021/om0201112

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of the stanna[1]ferrocenophane Fe(eta-C5H4)(2)Sn(tBu)(2) (8) toward transition-metal carbonyls was investigated. Insertion of an Fe(CO)4 fragment into an Sn-Cp bond of 8 was observed on treatment with Fe-2(CO)(9), forming the ferrostanna[2]ferrocenophane 9 whereas in the case Of Co-2(CO)(8), a highly unusual rearrangement/transfer of CO occurred, forming the ketone-bridged dimer 10.

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页码：2359 / 2361

页数：3

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