Azido-mediated systems showing different magnetic behaviors

被引：600

作者：

Zeng, Yong-Fei ^{[1
]}

Hu, Xin ^{[1
]}

Liu, Fu-Chen ^{[1
]}

Bu, Xian-He ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 02期

关键词：

END-TO-END; SINGLE-MOLECULE MAGNETS; HIGH-SPIN MOLECULES; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; BRIDGING LIGAND; HYDROTHERMAL SYNTHESIS; NICKEL(II) COMPLEXES; COPPER(II) CHAIN; SLOW RELAXATION;

D O I：

10.1039/b718581m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Azido has been one of the well used bridging ligands in the construction of magnetic molecule materials, which has stimulated considerable interest in magnetochemistry. This tutorial review is concentrated on the study of azido metal compounds with their magnetochemistry and consists of eight main sections. The first section offers an introduction to azido complexes and some important results obtained from magneto-structural correlation in azido complexes which will be referred to in the following sections. The next six sections give overviews of azido-mediated ferromagnets, ferrimagnets, canted (weak) ferromagnets, antiferromagnets, single molecule magnets (SMMs) and single chain magnets (SCMs), and metamagnets. The last section is the conclusion and gives a perspective of azido-mediated magnets.

引用

页码：469 / 480

页数：12

共 60 条

[1] Synthesis, structural characterization, magnetic behavior, and single crystal EPR spectra of three new one-dimensional manganese azido systems with FM, alternating FM-AF, and AF coupling [J].

Abu-Youssef, MAM ;

Escuer, A ;

Gatteschi, D ;

Goher, MAS ;

Mautner, FA ;

Vicente, R .

INORGANIC CHEMISTRY, 1999, 38 (25) :5716-5723

[2] A ferromagnetically coupled Mn19 aggregate with a record S=83/2 ground spin state [J].

Ako, Ayuk M. ;

Hewitt, Ian J. ;

Mereacre, Valeritt ;

Clerac, Rodolphe ;

Wernsdorfer, Wolfgang ;

Anson, Christopher E. ;

Powell, Annie K. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (30) :4926-4929

[3] Five new manganese-μ-azido 2D compounds synthesized in aqueous hydrazoic acid from pyrazine derivatives [J].

Bitschnau, B ;

Egger, A ;

Escuer, A ;

Mautner, FA ;

Sodin, B ;

Vicente, R .

INORGANIC CHEMISTRY, 2006, 45 (02) :868-876

[4] CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF [CU2(TMEN)2(N3)3](PF6) (TMEN = N,N,N',N'-TETRAMETHYLENEDIAMINE) - A COPPER(II) CHAIN COMPOUND WITH BOTH SINGLE SYMMETRICAL AND DOUBLE DISSYMMETRICAL END-TO-END AZIDO BRIDGES [J].

BKOUCHEWAKSMAN, I ;

BOILLOT, ML ;

KAHN, O ;

SIKORAV, S .

INORGANIC CHEMISTRY, 1984, 23 (26) :4454-4459

[5] A nonanuclear iron(II) single-molecule magnet [J].

Boudalis, AK ;

Donnadieu, B ;

Nastopoulos, V ;

Clemente-Juan, JM ;

Mari, A ;

Sanakis, Y ;

Tuchagues, JP ;

Perlepes, SP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (17) :2266-2270

[6] DINUCLEAR COPPER(II) CRYPTATES OF MACROCYCLIC LIGANDS - SYNTHESIS, CRYSTAL-STRUCTURE, AND MAGNETIC-PROPERTIES - MECHANISM OF THE EXCHANGE INTERACTION THROUGH BRIDGING AZIDO LIGANDS [J].

COMARMOND, J ;

PLUMERE, P ;

LEHN, JM ;

AGNUS, Y ;

LOUIS, R ;

WEISS, R ;

KAHN, O ;

MORGENSTERNBADARAU, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (23) :6330-6340

[7]

Coronado E., 1995, NATO ASI SERIES, V321

[8] Weak metamagnetic-like 1D manganese(II) complex with a double μ1,1-azido bridge:: A structure and magnetic study [J].

Das, A ;

Rosair, GM ;

El Fallah, MS ;

Ribas, J ;

Mitra, S .

INORGANIC CHEMISTRY, 2006, 45 (08) :3301-3306

[9] Synthesis and structural characterization of the one-dimensional [Cu(3-Clpy)2(N3)2]n complex (3-Clpy = 3-chloropyridine):: A singular ferrimagnetic chain with local SA = SB [J].

Escuer, A ;

Vicente, R ;

El Fallah, MS ;

Goher, MAS ;

Mautner, FA .

INORGANIC CHEMISTRY, 1998, 37 (17) :4466-4469

[10] A two-dimensional azido-based topologic ferrimagnet [J].

Escuer, A ;

Mautner, FA ;

Goher, MAS ;

Abu-Youssef, MAM ;

Vicente, R .

CHEMICAL COMMUNICATIONS, 2005, (05) :605-607

← 1 2 3 4 5 6 →