Perspective on "Zur quantentheorie der molekeln" -: !Born M, !Oppenheimer R (1927) Ann Phys 84:457

被引：47

作者：

Tully, JC ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

THEORETICAL CHEMISTRY ACCOUNTS | 2000年 / 103卷 / 3-4期

关键词：

adiabatic; nonadiabatic; potential-energy surface; Born-Oppenheimer approximation;

D O I：

10.1007/s002149900049

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Born-Oppenheimer approximation, introduced in the 1927 paper "On the quantum theory of molecules", provides the foundation for virtually all subsequent theoretical and computational studies of chemical binding and reactivity, as well as the justification for the universal "ball and stick" picture of molecules as atomic centers attached at fixed distances by electronic glue.

引用

页码：173 / 176

页数：4

共 5 条

[1]

Born M, 1927, ANN PHYS-BERLIN, V84, P0457

[2] UNIFIED APPROACH FOR MOLECULAR-DYNAMICS AND DENSITY-FUNCTIONAL THEORY [J].