Supramolecular gas-solid reaction between formic acid vapours and solid [CoIII(η5-C5H4COOH)(η5-C5H4COO)]

被引：27

作者：

Braga, D

Maini, L

Mazzotti, M

Rubini, K

Masic, A

Gobetto, R

Grepioni, F

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[2] Univ Turin, Dipartimento Chim IFM, I-10125 Turin, Italy

[3] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 20期

关键词：

D O I：

10.1039/b207581d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Exposure of the solid zwitterion [Co-III(eta(5)-C5H4COOH)(eta(5)-C5H4COO)] to vapours of formic acid quantitatively produces the co-crystal [Co-III(5-C5H4COOH)(eta(5)-C5H4COO)] [HCOOH] without proton transfer from formic acid to the deprotonated -COO- group on the zwitterion; formic acid can be quantitatively removed by mild thermal treatment, regenerating the starting material.

引用

收藏

页码：2296 / 2297

页数：2

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