Comb copolymer brush with chemically different side chains

被引：46

作者：

Stepanyan, R

Subbotin, A

ten Brinke, G

机构：

[1] Univ Groningen, Polymer Chem Lab, NL-9747 AG Groningen, Netherlands

[2] Univ Groningen, Ctr Mat Sci, NL-9747 AG Groningen, Netherlands

[3] Russian Acad Sci, Inst Petrochem Synthesis, Moscow 117912, Russia

来源：

MACROMOLECULES | 2002年 / 35卷 / 14期

关键词：

D O I：

10.1021/ma011441l

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An investigation of side chain microphase separation within a single comb copolymer molecule containing chemically different A and B side chains has been carried out. Expressions for the transition point chi(AB)* in a good (chi(AB)* similar to N-3/8), marginal (chi(AB)* similar to N-1/2), theta (chi(AB)(*) similar to N-2/3), and poor (chi(AB)* similar to N-1) solvent are derived both by a mean field calculation and by scaling arguments. Properties of the system below and above the transition point are described. Some unusual "bowlike" conformations are predicted for a single molecule in the microphase separated state in a good solvent.

引用

页码：5640 / 5648

页数：9

共 55 条

[1] POLYMERS GRAFTED TO A CONVEX SURFACE [J].