Phosphorus-containing dendrimers as multidentate ligands: Palladium, platinum, and rhodium complexes

被引：95

作者：

Bardaji, M ^{[1
]}

Kustos, M ^{[1
]}

Caminade, AM ^{[1
]}

Majoral, JP ^{[1
]}

Chaudret, B ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 03期

关键词：

D O I：

10.1021/om9606101

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New dendrimers 3-[G'(1)]-3-[G'(4)] possessing from 6 to 48 N(CH(2)PPh(2))(2) terminal groups are described. The corresponding Pd, Pt, and Ph complexes [N(CH(2)PPh(2))(2)MRR'](y) (y from 6 to 24; generations 1-3) [M = Pd: R = R' = Cl, Br; R = Cl, R' = Me; R = Br, R' = Me; R = Cl, R' = COMe; R = Cl, R' = norbornyl-COMe. M = Pt: R = R' = Br, Cl, Me; R = Br, R' = Me. M = Ph: R, R' = acac] are prepared by reacting 3-[G'(1)]-3-[G'(3)] with the appropriate transition metal complexes.

引用

页码：403 / 410

页数：8

共 63 条

[1] LARGE DENDRIMERIC ORGANOPLATINUM COMPLEXES
ACHAR, S
PUDDEPHATT, RJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (16) : 1895 - 1896
[2] ACHAR S, 1994, ANGEW CHEM INT EDIT, V33, P847, DOI 10.1002/anie.199408471
[3] ORGANOMETALLIC SILICON DENDRIMERS
ALONSO, B
CUADRADO, I
MORAN, M
LOSADA, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (22) : 2575 - 2576
[4] [Anonymous], TOP CURR CHEM
[5] PREPARATION AND PROPERTIES OF HYDROXO(METHYL)-1,2-BIS(DIPHENYLPHOSPHINO)ETHANEPLATINUM (II) - TRANS-INFLUENCE SERIES INCLUDING SIGMA-CARBON DONOR LIGANDS BASED ON PLATINUM-PHOSPHORUS COUPLING-CONSTANTS
APPLETON, TG
BENNETT, MA
[J]. INORGANIC CHEMISTRY, 1978, 17 (03) : 738 - 747
[6] ARDOIN N, 1995, B SOC CHIM FR, V132, P876
[7] ASTRUC D, 1992, NEW J CHEM, V16, P305
[8] DICARBONYL-BETA-DIKETONATO- + RELATED COMPLEXES OF RHODIUM(I)
BONATI, F
WILKINSON, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (SEP): : 3156 - &
[9] CAMINADE AM, 1995, MAIN GROUP CHEM NEWS, V3, P14
[10] AGGREGATION IN FLUID SOLUTION OF DENDRITIC SUPERMOLECULES MADE OF RUTHENIUM(II)-POLYPYRIDINE AND OSMIUM(II)-POLYPYRIDINE BUILDING-BLOCKS
CAMPAGNA, S
GIANNETTO, A
SERRONI, S
DENTI, G
TRUSSO, S
MALLAMACE, F
MICALI, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (06) : 1754 - 1758

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