Optimized Sn/SnSb lithium storage materials

被引:75
作者
Mukaibo, H
Osaka, T
Reale, P
Panero, S
Scrosati, B [1 ]
Wachtler, M
机构
[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
[2] Waseda Univ, Tokyo, Japan
基金
日本学术振兴会;
关键词
lithium metal storage; anode; lithium-ion batteries;
D O I
10.1016/j.jpowsour.2003.12.042
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the synthesis of SnSb-based intermetallic with improved morphology. The electrochemical characterization shows that these materials have a good electrode behavior in a lithium cell. Capacities exceeding 800 mAh/g with a charge-discharge efficiency approaching 100%, have been obtained. In addition, the percent of the initial irreversible capacity is moderate. The capacity decreases upon cycling quite likely due to a still not optimized electrode structure. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:225 / 228
页数:4
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