Direct oxidation of jet fuels and Pennsylvania crude oil in a solid oxide fuel cell

被引:54
作者
Zhou, ZF
Gallo, C
Pague, MB
Schobert, H
Lvov, SN [1 ]
机构
[1] Penn State Univ, Energy Inst, University Pk, PA 16802 USA
[2] Penn State Univ, Dept Energy & Geoenvironm Engn, University Pk, PA 16802 USA
关键词
solid oxide fuel cell; direct oxidation; hydrocarbon fuels; Cu-ceria anode; Pennsylvania crude oil; jet fuel;
D O I
10.1016/j.jpowsour.2003.12.044
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A Cu-ceria solid oxide fuel cell (SOFC) is shown to generate electric power using jet fuels and Pennsylvania crude oil through direct oxidation of the fuels. The liquid fuels contained up to 910 ppm of sulfur and were injected into the anode compartment either with or without N-2 dilution. The performance of the fuel cell was stable over 30 h for jet fuels and Pennsylvania crude oil without N-2 dilution whereas N-2 dilution prolonged the stable power generation up to 100 h for jet fuel and up to 80 h for Pennsylvania crude oil. The generated power density was about 0.1 W cm(-2) for both fuels. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:181 / 187
页数:7
相关论文
共 22 条
[1]  
BADGER MW, 2001, FUELS NEWSLETT, V26, P10
[2]  
BUTNARK S, 2003, AM CHEM SOC DIV FUEL, V48, P158
[3]  
Gorte RJ, 2000, ADV MATER, V12, P1465, DOI 10.1002/1521-4095(200010)12:19<1465::AID-ADMA1465>3.0.CO
[4]  
2-9
[5]   Novel SOFC anodes for the direct electrochemical oxidation of hydrocarbon [J].
Gorte, RJ ;
Kim, H ;
Vohs, JM .
JOURNAL OF POWER SOURCES, 2002, 106 (1-2) :10-15
[6]  
GORTE RJ, 2003, Patent No. 6589680
[7]  
GRUSE WA, 1942, CHEM TECHNOLOGY PETR, pCH1
[8]  
GRUSE WA, 1928, PETROLEUM ITS PRODUC, pCH1
[9]  
Hunt J., 1996, PETROLEUM GEOCHEMIST
[10]   Direct oxidation of liquid fuels in a solid oxide fuel cell [J].
Kim, H ;
Park, S ;
Vohs, JM ;
Gorte, RJ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (07) :A693-A695