Raman spectroscopic study on photochromic reaction of a diarylethene derivative

被引：26

作者：

Okabe, C

Tanaka, N

Fukaminato, T

Kawai, T

Irie, M

Nibu, Y

Shimada, H

Goldberg, A

Nakamura, S

Sekiya, H

机构：

[1] Kyushu Univ, Grad Sch Mol Chem, Fac Sci, Dept Chem,Higashi Ku, Fukuoka 8128581, Japan

[2] Kyushu Univ, Grad Sch Engn, Japan Sci & Technol Corp, JST,Dept Chem & Biochem,Higashi Ku, Fukuoka 8128581, Japan

[3] CREST, Fukuoka 8128581, Japan

[4] Fukuoka Univ, Fac Sci, Dept Chem, Zyounan Ku, Fukuoka 8140180, Japan

[5] Mitsubishi Chem Corp, MCC Grp Sci, Computat Modeling Mat Lab, Aoba Ku, Yokohama, Kanagawa 2278502, Japan

[6] Mitsubishi Chem Corp, Technol Res Ctr, Aoba Ku, Yokohama, Kanagawa 2278502, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 357卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(02)00451-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photochromic reaction of 1,2-bis(3-methyl-2-thienyl)perfluorocyclopentene has been studied by FT-Raman spectroscopy. The Raman bands in the 1300-1700 cm(-1) region of the open-ring isomer of 1,2-bis(3-methyl-2-thienyl)perfluorocyclopentene are clearly distinguished from those of the closed-ring isomer. The vibrational assignment has been made by measuring the polarized Raman spectrum and density functional theory calculations at the B3LYP/6-31G** level. (C) 2002 Published by Elsevier Science B.V.

引用

页码：113 / 118

页数：6

共 26 条

[1] PHOTOCHROMIC HETEROCYCLIC FULGIDES .2. ELECTROCYCLIC REACTIONS OF (E)-ALPHA-2,5-DIMETHYL-3-FURYLETHYLIDENE(ALKYL-SUBSTITUTED METHYLENE)-SUCCINIC ANHYDRIDES [J].