Synthesis of new trialkylsilylmethyloxazinones via intramolecular trapping of beta-silyl carbocations by an N-Boc group

被引：31

作者：

BrocherieuxLanoy, S ^{[1
]}

Dhimane, H ^{[1
]}

Poupon, JC ^{[1
]}

Vanucci, C ^{[1
]}

Lhommet, G ^{[1
]}

机构：

[1] UNIV PARIS 06,LAB CHIM HETEROCYCLES,URA 408,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 15期

关键词：

D O I：

10.1039/a703902f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Boc amino ethers la-e when treated with allyltrialkylsilanes in the presence of TiCl4 afford the expected allylation compounds 2a-e and/or the unprecedented silylated oxazinones 3a-e or 4a-e.

引用

页码：2163 / 2165

页数：3

共 21 条

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