'Oxenoid' oxygen insertion vs a radical mechanism in the oxidation of alkanes and alcohols: The case of aromatic peracids

被引：24

作者：

Bravo, A ^{[1
]}

Fontana, F ^{[1
]}

Minisci, F ^{[1
]}

Serri, A ^{[1
]}

机构：

[1] POLITECN MILAN,DIPARTIMENTO CHIM,I-20131 MILAN,ITALY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 15期

关键词：

D O I：

10.1039/cc9960001843

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adamantane is oxidised by MCPBA in a free-radical process, whose selectivity is discussed; by this method, cyclohexanol can be directly oxidised to caprolactone.

引用

页码：1843 / 1844

页数：2

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