Synthesis and structural characterization of the yttrium(III) polyalcohol complexes: [Y{(HOCH2)(3)CCH3}(2)Cl-2]Cl.MeOH, [Y{(HOCH2)(3)CN(CH2CH2OH)(2)}Cl-2(MeOH)]Cl and [Y{(HOCH2)(3)CCH2}(2)(NO3)(H2O)](NO3)(2)

被引：17

作者：

Chen, Q ^{[1
]}

Chang, YD ^{[1
]}

Zubieta, J ^{[1
]}

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

来源：

INORGANICA CHIMICA ACTA | 1997年 / 258卷 / 02期

关键词：

crystal structures; yttrium complexes; polyalcohol complexes;

D O I：

10.1016/S0020-1693(96)05514-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of YCl3 with the polyalcohols (HOCH2)(3)CCH3 and (HOCH2)(3)CN(CH2CH2OH)(2) in MeOH yielded [Y{(HOCH2O3CCH3}(2)Cl-2]Cl . MeOH (1) and [Y{(HOCH2)(3)CN(CH2CH2OH)(2)}Cl-2(MeOH)]Cl (2), respectively. Similarly, the reaction of Y(NO3)(3) with (HOCH2)(3)CCH3 in ethanol gave [Y{(HOCH2)(3)CCH3}(2)(NO3)](H2O)](NO3)(2) (3). In all cases, the ligands are present in the alcohol form rather than the alkoxy form. Crystal data: C11H28O7Cl3Y (1): orthorhombic Pna2(1), a=9.218(1), b=23.501(3), c=9.222(1) Angstrom, V=1997.8(9) Angstrom(3), Z=4. C9H23O6NCl3Y (2). triclinic P (1) over bar, a=8.859(3), b=14.336(4), c=6.975(2) Angstrom, alpha=103.85(1), beta=105.02(2), gamma=96.10(2)degrees, V=817.3(4) Angstrom(3), Z=2; C10H26O16N3Y, monoclinic P2(1)/c, a=9.354(2), b=11.750(3), c=19.7211(4) Angstrom, beta=95.87(1)degrees, V=2156.2(9) Angstrom(3), Z=4.

引用

页码：257 / 262

页数：6

共 17 条

[1]

ABRAMS MJ, 1991, INORG CHEM, V39, P2031

[2]

[Anonymous], 1974, Critical Stability Constants

[3]

CAMERA L, 1994, J NUCL MED, V35, P882

[4]

CHINOL M, 1987, J NUCL MED, V28, P1465

[5]

COLTON FA, 1980, ADV INORGANIC CHEM C, P985

[6]

CREAGH DD, 1992, INT TABLEX XRAY CRYS, VC

[7]

Cromer D. T., 1974, INT TABLES XRAY CRYS, V4

[8]

DESHPANDE SV, 1988, J NUCL MED, V29, P217

[9] SYNTHESIS AND CHARACTERIZATION OF VOLATILE SODIUM YTTRIUM FLUOROALKOXIDES - STRUCTURE OF NA3Y(OCH(CF3)(2))(6)(THF)(3) AND NA2Y(OCME(CF3)(2))(5)(THF)(3) [J].

LAURENT, F ;

HUFFMAN, JC ;

FOLTING, K ;

CAULTON, KG .

INORGANIC CHEMISTRY, 1995, 34 (15) :3980-3985

[10]

*MOL STRUCT CORP, 1992, TEXSAN TEXR STRUCT A

← 1 2 →