Effect of the penetration of Li atoms into the Pd surface on thermodynamic properties of the Pd-H system

被引：11

作者：

Uchida, H

Sato, M

Cui, W

Tabata, T

Kumagai, M

Takano, H

Kondo, T

机构：

[1] Tokai Univ, Sch Engn, Dept Appl Phys, Hiratsuka, Kanagawa 2591292, Japan

[2] Kanagawa High Technol Fdn, Kawasaki, Kanagawa 2130012, Japan

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1999年 / 293卷

关键词：

Pd hydride; penetration of Li into Pd; Li-Pd alloys; interaction of hydrogen with Li;

D O I：

10.1016/S0925-8388(99)00391-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study reports the effect of the penetration of Li atoms into the Pd surface on the pressure-composition-temperature relation of the Pd-H system and on the heats of reactions of hydrogen. A heat treatment of Pd in a 1 M LiOH solution induces the penetration of Li atoms into Pd even at 353 K. The marked enhancement about by 90-100% for the formation of hydrogen solid solution, and about by 29% for the formation of PdH1-x hydride phase seems to be attributed to strong interactions of hydrogen with the Li atoms penetrated from the LiOH during the pretreatment. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：30 / 33

页数：4

共 9 条

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Fromm E., 1976, GASE KOHLENSTOFF MET, P638

[2] Thermodynamic properties of hydrogen in fine Pd powders [J].