Large negative cubic hyperpolarizability for the spin-crossover compound cis-bis(thiocyanato)bis[N-(2-pyridylmethylene)aminobiphenyl]iron(II)

被引：35

作者：

Letard, JF ^{[1
]}

Montant, S ^{[1
]}

Guionneau, P ^{[1
]}

Martin, P ^{[1
]}

LeCalvez, A ^{[1
]}

Freysz, E ^{[1
]}

Chasseau, D ^{[1
]}

Lapouyade, R ^{[1
]}

Kahn, O ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,F-33405 TALENCE,FRANCE

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 08期

关键词：

D O I：

10.1039/a700019g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of a spin-crossover iron(II) compound with a large negative third-order polarizability, associated with an instantaneous electronic response, is reported; magnetic measurements show that this compound, cis-bis(thiocyanato)bis [N-(2-pyridylmethylene)aminobiphenyl]iron(II), characterized by X-ray structural data is in the high-spin form at room temperature.

引用

页码：745 / 746

页数：2

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