Cationic species can be produced in soluble methane monooxygenase-catalyzed hydroxylation reactions; radical intermediates are not formed

被引：66

作者：

Choi, SY

Eaton, PE

Kopp, DA

Lippard, SJ ^{[1
]}

Newcomb, M

Shen, RN

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

[2] MIT, Dept Chem, Cambridge, MA 02139 USA

[3] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1999年 / 121卷 / 51期

关键词：

D O I：

10.1021/ja993259u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：12198 / 12199

页数：2

共 23 条

[1] Regiochemical variations in reactions of methylcubane with tert-butoxyl radical, cytochrome P-450 enzymes, and a methane monooxygenase system
Choi, SY
Eaton, PE
Hollenberg, PF
Liu, KE
Lippard, SJ
Newcomb, M
Putt, DA
Upadhyaya, SP
Xiong, YS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (28) : 6547 - 6555
[2] PICOSECOND RADICAL KINETICS - BOND-CLEAVAGE OF THE CUBYLCARBINYL RADICAL
CHOI, SY
EATON, PE
NEWCOMB, M
YIP, YC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (16) : 6326 - 6329
[3] BRIDGEHEAD CARBOCATIONS - CORRELATION BETWEEN MP2/6-31G-ASTERISK CATION ENERGIES OF SOME CAGED CATIONS AND THE SOLVOLYSIS RATES OF THEIR PRECURSOR TRIFLATES
DELLA, EW
JANOWSKI, WK
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (24) : 7756 - 7759
[4] CUBYL CATION
EATON, PE
YANG, CX
XIONG, YS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (08) : 3225 - 3226
[5] THE PREPARATION AND FATE OF CUBYLCARBINYL RADICALS
EATON, PE
YIP, YC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) : 7692 - 7697
[6] CUBANES - STARTING MATERIALS FOR THE CHEMISTRY OF THE 1990S AND THE NEW CENTURY
EATON, PE
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (11): : 1421 - 1436
[7] FOX BG, 1990, METHOD ENZYMOL, V188, P191
[8] Probing the mechanism of C-H activation:: Oxidation of methylcubane by soluble methane monooxygenase from Methylosinus trichosporium OB3b
Jin, Y
Lipscomb, JD
[J]. BIOCHEMISTRY, 1999, 38 (19) : 6178 - 6186
[9] Picosecond radical kinetics. Rate constants for ring openings of (2-alkoxy-3-phenylcyclopropyl)methyl radicals
LeTadicBiadatti, MH
Newcomb, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (07): : 1467 - 1473
[10] RADICAL CLOCK SUBSTRATE PROBES AND KINETIC ISOTOPE EFFECT STUDIES OF THE HYDROXYLATION OF HYDROCARBONS BY METHANE MONOOXYGENASE
LIU, KE
JOHNSON, CC
NEWCOMB, M
LIPPARD, SJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (03) : 939 - 947

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