A new synthon for the incorporation of [60]fullerene in macrocycles

被引：6

作者：

Rapenne, G ^{[1
]}

Diederich, F ^{[1
]}

机构：

[1] ETH Zentrum, Organ Chem Lab, CH-8092 Zurich, Switzerland

来源：

NEW JOURNAL OF CHEMISTRY | 1999年 / 23卷 / 12期

关键词：

D O I：

10.1039/a908544k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bis(methano)fullerenedicarboxylic acid was obtained in four steps from C-60 as a new synthon for incorporation of the carbon sphere into macrocycles; the preparation of the target compound involves the tether-directed synthesis of a macrocyclic cis-2 bis(malonic acid diester) adduct of C-60, followed by selective ester deprotection, decarboxylation of the formed bis(malonic acid monoester) and removal of the tether.

引用

页码：1125 / 1127

页数：3

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