Biomimetic transfer hydrogenation of ketones with iron porphyrin catalysts

被引：89

作者：

Enthaler, Stephan ^{[1
]}

Erre, Giulia ^{[1
]}

Tse, Man Kin ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 46期

关键词：

D O I：

10.1016/j.tetlet.2006.09.058

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

For the first time in situ generated iron porphyrins have been applied as homogeneous catalysts for the transfer hydrogenation of ketones. Using 2-propanol as hydrogen source various ketones are reduced to the corresponding alcohols in good to excellent yield and selectivity. Under optimized reaction conditions high catalyst turnover frequencies up to 642 h(-1) are achieved. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：8095 / 8099

页数：5

共 53 条

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