From carbon dioxide to methane: Homogeneous reduction of carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes

被引：204

作者：

Matsuo, Tsukasa ^{[1
]}

Kawaguchi, Hiroyuki ^{[1
]}

机构：

[1] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448787, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 38期

关键词：

D O I：

10.1021/ja0647250

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mixture of a zirconium benzyl phenoxide complex and tris(pentafluorophenyl)borane is reported that catalyzes the hydrosilation reaction of carbon dioxide to generate methane via a bis(silyl)acetal intermediate. Copyright © 2006 American Chemical Society.

引用

页码：12362 / 12363

页数：2

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