Controllable Synthesis of Hollow Si Anode for Long-Cycle-Life Lithium-Ion Batteries

被引：238

作者：

Huang, Xingkang ^{[1
]}

Yang, Joseph ^{[1
]}

Mao, Shun ^{[1
]}

Chang, Jingbo ^{[1
]}

Hallac, Peter B. ^{[2
]}

Fell, Christopher R. ^{[2
]}

Metz, Bernhard ^{[2
]}

Jiang, Junwei ^{[2
]}

Hurley, Patrick T. ^{[2
]}

Chen, Junhong ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Mech Engn, Milwaukee, WI 53211 USA

[2] Johnson Controls, Global Technol & Innovat, Power Solut, Milwaukee, WI 53209 USA

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 25期

关键词：

SILICON NANOWIRES; ELECTROCHEMICAL LITHIATION; PERFORMANCE; NANOPARTICLES; COMPOSITE; FILM; ELECTRODE; CRYSTALLIZATION; NANOCOMPOSITES; CARBONATE;

D O I：

10.1002/adma.201400578

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A versatile and surfactant-free method is developed to synthesize hollow Si materials using carbonates as templates without the use of hazardous hydrofluoric acid. The morphology of Si is controllable from hollow cubes, spheres, and tubes, to flowers and other shapes. Such hollow Si materials as anodes of lithium-ion batteries show excellent cyclic performance, which is promising for practical applications.

引用

页码：4326 / 4332

页数：7

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