Cationic gold(I) complexes:: Highly alkynophilic catalysts for the exo- and endo-cyclization of enynes

被引：548

作者：

Nieto-Oberhuber, C ^{[1
]}

Muñoz, MP ^{[1
]}

Buñuel, E ^{[1
]}

Nevado, C ^{[1
]}

Cárdenas, DJ ^{[1
]}

Echavarren, AM ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 18期

关键词：

alkynes; cyclization; density functional calculations; gold; rearrangements;

D O I：

10.1002/anie.200353207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As good as gold: Alkynophilic cationic gold(i) complexes are very active catalysts for reactions of enynes that proceed exclusively through cyclopropyl carbene complexes as intermediates (see scheme). With such catalysts, the first examples of endocyclic skeletal rearrangements under mild conditions have been observed.

引用

页码：2402 / 2406

页数：5

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