Single crystal of C60Fx and the X-ray structural analysis

被引：21

作者：

Okino, F ^{[1
]}

Kawasaki, S ^{[1
]}

Fukushima, Y ^{[1
]}

Kimura, M ^{[1
]}

Nakajima, T ^{[1
]}

Touhara, H ^{[1
]}

机构：

[1] SHINSHU UNIV, FAC ENGN, DEPT CHEM & MAT ENGN, NAGANO 380, JAPAN

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1996年 / 4卷 / 05期

关键词：

D O I：

10.1080/10641229608001149

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Single crystals of fluorinated fullerene C60Fx have been grown by sublimation. The crystal, ca. C60F46, has an fcc lattice with the cell constant 17.158(3) Angstrom. The rotating molecules can be regarded as two inner spherical shells of carbon with radii 3.13 and 3.83 Angstrom and an outer spherical shell of fluorine at 5.12 Angstrom away from the center. PM3 calculations on C60F44,46,48 support the electron distribution in the ca. C60F46 determined by the X-ray structural analysis.

引用

页码：873 / 885

页数：13

共 10 条

[1] COMPRESSIBILITY OF SOLID C60 [J].

FISCHER, JE ;

HEINEY, PA ;

MCGHIE, AR ;

ROMANOW, WJ ;

DENENSTEIN, AM ;

MCCAULEY, JP ;

SMITH, AB .

SCIENCE, 1991, 252 (5010) :1288-1290

[2] SELECTIVE SYNTHESIS AND STRUCTURE DETERMINATION OF C60F48 [J].

GAKH, AA ;

TUINMAN, AA ;

ADCOCK, JL ;

SACHLEBEN, RA ;

COMPTON, RN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (02) :819-820

[3] ORIENTATIONAL ORDERING TRANSITION IN SOLID C60 [J].

HEINEY, PA ;

FISCHER, JE ;

MCGHIE, AR ;

ROMANOW, WJ ;

DENENSTEIN, AM ;

MCCAULEY, JP ;

SMITH, AB ;

COX, DE .

PHYSICAL REVIEW LETTERS, 1991, 66 (22) :2911-2914

[4] FLUORINATION OF BUCKMINSTERFULLERENE [J].

HOLLOWAY, JH ;

HOPE, EG ;

TAYLOR, R ;

LANGLEY, GJ ;

AVENT, AG ;

DENNIS, TJ ;

HARE, JP ;

KROTO, HW ;

WALTON, DRM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (14) :966-969

[5] FLUORINATED FULLERENES - SYNTHESIS, STRUCTURE, AND PROPERTIES [J].

KNIAZ, K ;

FISCHER, JE ;

SELIG, H ;

VAUGHAN, GBM ;

ROMANOW, WJ ;

COX, DM ;

CHOWDHURY, SK ;

MCCAULEY, JP ;

STRONGIN, RM ;

SMITH, AB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) :6060-6064

[6] CHEMICAL BONDING AND ELECTROCHEMICAL REDUCTION OF FLUORINATED FULLERENE [J].

NAKAJIMA, T ;

MATSUO, Y .

CARBON, 1992, 30 (07) :1119-1120

[7]

Okin F., 1993, Fullerene Science and Technology, V1, P425, DOI 10.1080/15363839308011909

[8]

OKINO F, 1994, T MRS JAP, V14, P1205

[9] FLUORINATED FULLERENES [J].

SELIG, H ;

LIFSHITZ, C ;

PERES, T ;

FISCHER, JE ;

MCGHIE, AR ;

ROMANOW, WJ ;

MCCAULEY, JP ;

SMITH, AB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) :5475-5476

[10] HYPERFLUORINATION OF BUCKMINSTERFULLERENE - CRACKING THE SPHERE [J].

TUINMAN, AA ;

GAKH, AA ;

ADCOCK, JL ;

COMPTON, RN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (13) :5885-5886

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