Fitting of different models for water vapour sorption on potato starch granules

被引:19
作者
Czepirski, L
Komorowska-Czepirska, E
Szymonska, J
机构
[1] Stanislaw Staszic Univ Min & Met, Fac Fuels & Energy, PL-30059 Krakow, Poland
[2] Univ Agr, Dept Chem, PL-30059 Krakow, Poland
关键词
water sorption; bio-based adsorbents; BET model; fractal dimension;
D O I
10.1016/S0169-4332(02)00050-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Water vapour adsorption isotherms for native and modified potato starch were investigated. To obtain the best fit for the experimental data several models based on the BET approach were evaluated. The hypothesis that water is adsorbed on the starch granules at the primary and secondary adsorption sites as well as a concept considering the adsorbent fractality were also tested. It was found, that the equilibrium adsorption points in the examined range of relative humidity (0.03-0.90) were most accurately predicted by using a three-parameter model proposed by Kats and Kutarov. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:150 / 153
页数:4
相关论文
共 12 条
[1]   Chemistry and properties of starch based desiccants [J].
Beery, KE ;
Ladisch, MA .
ENZYME AND MICROBIAL TECHNOLOGY, 2001, 28 (7-8) :573-581
[2]  
CIEMBRONIEWICZ A, 1985, PRZEM CHEM, V66, P265
[3]   A modified BET equation for polylayer adsorption [J].
Kats, BM ;
Kutarov, VV .
ADSORPTION SCIENCE & TECHNOLOGY, 1998, 16 (04) :257-262
[4]   Adsorption of water vapour by chemisorptive fibre with different counter-ions [J].
Kats, BM ;
Kutarov, VV ;
Kutovaya, LM .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1999, 157 (1-3) :95-99
[5]  
KATS BM, 1991, ZH PRIKL KHIM, V64, P846
[6]   Non-contact AFM investigation of influence of freezing process on the surface structure of potato starch granule [J].
Krok, F ;
Szymonska, J ;
Tomasik, P ;
Szymonski, M .
APPLIED SURFACE SCIENCE, 2000, 157 (04) :382-386
[7]   Biobased adsorbents for drying of gases [J].
Ladisch, MR .
ENZYME AND MICROBIAL TECHNOLOGY, 1997, 20 (03) :162-164
[8]  
MASCAN M, 1997, J FOOD ENG, V33, P227
[9]   FRACTAL STRUCTURE OF DEFORMED POTATO STARCH AND ITS SORPTION CHARACTERISTICS [J].
NAGAI, T ;
YANO, T .
JOURNAL OF FOOD SCIENCE, 1990, 55 (05) :1334-1337
[10]  
PFEIFER P, 1997, STUDIES SURFACE SCI, V104