Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts

被引：216

作者：

Clark, Timothy J.

Russell, Christopher A.

Manners, Ian

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 30期

关键词：

D O I：

10.1021/ja062217k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metal catalysis represents a relatively unexplored but potentially useful route to form bonds between main group elements. Previous work in the area of amine-borane adduct dehydrocoupling has exclusively employed late transition metal (e.g., Rh) catalysts which were found to predominantly operate via a heterogeneous mechanism. Herein, we present a new, early transition-metal-catalyzed, homogeneous system which exhibits higher activity. Copyright © 2006 American Chemical Society.

引用

页码：9582 / 9583

页数：2

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