Photochromic thiophene oligomers based on bisthienylethene: syntheses, photochromic and two-photon properties

被引:85
作者
Feng, Yanli
Yan, Yongli
Wang, Sheng
Zhu, Weihong
Qian, Shixiong
Tian, He [1 ]
机构
[1] E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China
[2] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China
[3] Fudan Univ, Dept Phys, Shanghai 200433, Peoples R China
关键词
D O I
10.1039/b608545h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of novel, functional symmetric and unsymmetric photochromic thiophene oligomers based on bisthienylethenes (BTEs) were synthesized via control of the reaction condition with a Suzuki coupling method. Their optical, photochromic quantum yields, two-photon and electrochemical properties in THF as well as in poly( methylmethacrylate) ( PMMA) films were measured and discussed. The fluorescence emission can be tuned reversibly by alternating irradiation with UV and visible light. These BTEs could be used as nanowires, fluorescent switch and electrochemical switch.
引用
收藏
页码:3685 / 3692
页数:8
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