A new example of dynamic kinetic resolution:: aminolysis of α-sulfinyl γ-unsaturated dithioesters

被引：5

作者：

Alayrac, C

Metzner, P

机构：

[1] ISMRA, CNRS, Lab Chim Mol & Thioorgan, F-14050 Caen, France

[2] Univ Caen, F-14050 Caen, France

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 15期

关键词：

D O I：

10.1016/S0040-4039(00)00204-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aminolysis of (2S*,SS*)-dithioesters 1a-d by dimethylamine proceeded under dynamic kinetic control, affording (2R*,SS*)-thioamides 2a-d with reverse configuration at the asymmetric carbon centre. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2537 / 2539

页数：3

共 7 条

[1]

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[2] First examples of a Claisen rearrangement stereocontrolled by a sulfinyl group: Synthesis of novel alpha-sulfinyl dithioesters [J].

Alayrac, C ;

Fromont, C ;

Metzner, P ;

Anh, NT .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (04) :371-374

[3]

Kagan H.B., 2007, TOPICS STEREOCHEMIST, V18, P249, DOI 10.1002/9780470147276.ch4

[4]

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[5]

SCHAUMANN E, 1991, COMPREHENSIVE ORGANI, V6, P419

[6]

TAO NS, 1972, Z CHEM, V12, P133

[7] DYNAMIC KINETIC RESOLUTION [J].

WARD, RS .

TETRAHEDRON-ASYMMETRY, 1995, 6 (07) :1475-1490

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