Transition metal-catalyzed ring-opening polymerization (ROP) of strained, silicon-bridged bis(benzene)chromium complexes

被引：33

作者：

Berenbaum, A ^{[1
]}

Manners, I ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

DALTON TRANSACTIONS | 2004年 / 14期

关键词：

D O I：

10.1039/b406873d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silicon-based bis(benzene)chromium complexes (sila[1]chromarenophanes) undergo facile transition metal-catalyzed ROP at ambient temperature in the presence of Karstedt's catalyst to yield polychromarenysilanes, the first homopolymers with main chains of Cr(arene)(2) and organosilane units.

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页码：2057 / 2058

页数：2

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