Synthesis of crossed [2+2] photocycloadducts: A novel approach to the synthesis of bridged bicyclic alkenes

被引：30

作者：

Crimmins, MT ^{[1
]}

Hauser, EB ^{[1
]}

机构：

[1] Univ N Carolina, Venable & Kenan Labs Chem, Chapel Hill, NC 27599 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 03期

关键词：

D O I：

10.1021/ol991272d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A solution to the synthesis of "crossed" intramolecular [2 + 2] photocycloadducts has been achieved. Through the use of a temporary heteroatom linker, the equivalent of a crossed photocycloadduct can be accessed at the expensive of the normal "straight" adduct, Selectivity as high as 94:6 for the "crossed" adduct has been observed.

引用

页码：281 / 284

页数：4

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