New direct hydroxylation of benzene with oxygen in the presence of hydrogen over bifunctional ion-exchange resins

被引：63

作者：

Laufer, W ^{[1
]}

Hoelderich, WF ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Dept Chem Technol & Heterogeneous Catalysis, D-52074 Aachen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 16期

关键词：

D O I：

10.1039/b204033f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Benzene was hydroxylated directly to phenol with oxygen in the presence of hydrogen over Pt/Pd containing acid resins such as Amberlyst and Nafion/silica composites; over the latter materials the best results were obtained.

引用

页码：1684 / 1685

页数：2

共 13 条

[1]

GOSSER LW, 1989, Patent No. 342047

[2] Nafion resin-silica nanocomposite solid acid catalysts. Microstructure-processing-property correlations [J].

Harmer, MA ;

Sun, Q ;

Vega, AJ ;

Farneth, WE ;

Heidekum, A ;

Hoelderich, WF .

GREEN CHEMISTRY, 2000, 2 (01) :7-14

[3] PD/SIO2 CATALYST FOR OXIDATION OF BENZENE TO PHENOL [J].

KUNAI, A ;

KITANO, T ;

KURODA, Y ;

LIFEN, J ;

SASAKI, K .

CATALYSIS LETTERS, 1990, 4 (02) :139-144

[4] Direct oxidation of propylene and other olefins on precious metal containing Ti-catalysts [J].

Laufer, W ;

Hoelderich, WF .

APPLIED CATALYSIS A-GENERAL, 2001, 213 (02) :163-171

[5]

LAUFER W, 1999, P 12 INT ZEOL C JUL, P1351

[6] Synthesis of propylene oxide from propylene, oxygen, and hydrogen catalyzed by palladium-platinum-containing titanium silicalite [J].

Meiers, R ;

Dingerdissen, U ;

Holderich, WF .

JOURNAL OF CATALYSIS, 1998, 176 (02) :376-386

[7]

MIYAKE T, 1991, Patent No. 03178946

[8] Direct hydroxylation of aromatics to their corresponding phenols catalysed by H-[Al]ZSM-5 zeolite [J].

Motz, JL ;

Heinichen, H ;

Holderich, WF .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1998, 136 (02) :175-184

[9] Generation of active oxygen species on solid surfaces. Opportunity for novel oxidation technologies over zeolites [J].

Panov, GI ;

Uriarte, AK ;

Rodkin, MA ;

Sobolev, VI .

CATALYSIS TODAY, 1998, 41 (04) :365-385

[10]

PASSONI LC, 1998, J MOL CATAL, V134, P129

← 1 2 →