Lewis acid-mediated displacements of alkoxydioxolanes: Synthesis of a 1,2-dioxolane natural product

被引：36

作者：

Dussault, PH ^{[1
]}

Liu, XJ ^{[1
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 09期

关键词：

D O I：

10.1021/ol990954y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Addition of electron-rich alkenes to the peroxycarbenium ions derived from Lewis acid-mediated ionization of 8-alkoxy-1,2-dioxolanes provides an efficient route for the synthesis of substituted 1,2-dioxolanes. The methodology is illustrated with a rapid synthesis of a 1,2-dioxolane natural product related to the plakinic acids.

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页码：1391 / 1393

页数：3

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