Unusual Magnetic Properties of Size-Controlled Iron Oxide Nanoparticles Grown in a Nanoporous Matrix with Tunable Pores

被引:43
作者
Alam, Sher [1 ]
Anand, Chokkalingam [1 ,3 ]
Ariga, Katsuhiko [1 ]
Mori, Toshiyuki [2 ]
Vinu, Ajayan [1 ]
机构
[1] Natl Inst Mat Sci, WPI Res Ctr Mat Nanoarchitecton MANA, Int Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan
[2] Natl Inst Mat Sci, Nanoion Mat Grp, Tsukuba, Ibaraki 3050044, Japan
[3] Anna Univ, Dept Chem, Madras 600025, Tamil Nadu, India
关键词
iron; magnetic properties; mesoporous supports; nanostructures; silica; MESOPOROUS MOLECULAR-SIEVES; CRYSTALLINE;
D O I
10.1002/anie.200901570
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fully loaded: A facile nanosieve approach for the preparation of Fe 2O3 nanoparticles that have uniform and tunable sizes and are highly dispersed over a mesoporous support is achieved by the simple adjustment of the pore diameter of the template matrix (see picture). The nanoparticles are very small (6.5-9.0 nm) and show superior magnetic properties compared to pure Fe2O3 nanoparticles prepared without using a support. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7358 / 7361
页数:4
相关论文
共 13 条
[1]   Ordered iron oxide nanotube arrays of controlled geometry and tunable magnetism by atomic layer deposition [J].
Bachmann, Julien ;
Jing, Jing ;
Knez, Mato ;
Barth, Sven ;
Shen, Hao ;
Mathur, Sanjay ;
Goesele, Ulrich ;
Nielsch, Kornelius .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (31) :9554-+
[2]   Mechanical stability and porosity analysis of large-pore SBA-15 mesoporous molecular sieves by mercury porosimetry and organics adsorption [J].
Hartmann, M ;
Vinu, A .
LANGMUIR, 2002, 18 (21) :8010-8016
[3]   Synthesis of highly crystalline and monodisperse maghemite nanocrystallites without a size-selection process [J].
Hyeon, T ;
Lee, SS ;
Park, J ;
Chung, Y ;
Bin Na, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (51) :12798-12801
[4]   ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].
KRESGE, CT ;
LEONOWICZ, ME ;
ROTH, WJ ;
VARTULI, JC ;
BECK, JS .
NATURE, 1992, 359 (6397) :710-712
[5]   Kinetics of monodisperse iron oxide nanocrystal formation by "heating-up" process [J].
Kwon, Soon Gu ;
Piao, Yuanzhe ;
Park, Jongnam ;
Angappane, Subramanian ;
Jo, Younghun ;
Hwang, Nong-Moon ;
Park, Je-Geun ;
Hyeon, Taeghwan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (41) :12571-12584
[6]   Nanocrystalline iron oxide aerogels as mesoporous magnetic architectures [J].
Long, JW ;
Logan, MS ;
Rhodes, CP ;
Carpenter, EE ;
Stroud, RM ;
Rolison, DR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (51) :16879-16889
[7]  
Lu A. -H., 2007, ANGEW CHEM, V119, P1242, DOI DOI 10.1002/ANGE.200602866
[8]   Magnetic nanoparticles:: Synthesis, protection, functionalization, and application [J].
Lu, An-Hui ;
Salabas, E. L. ;
Schueth, Ferdi .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (08) :1222-1244
[9]   Benzyl alcohol and transition metal chlorides as a versatile reaction system for the nonaqueous and low-temperature synthesis of crystalline nano-objects with controlled dimensionality [J].
Niederberger, M ;
Bard, MH ;
Stucky, GD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (46) :13642-13643
[10]   Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices [J].
Sun, SH ;
Murray, CB ;
Weller, D ;
Folks, L ;
Moser, A .
SCIENCE, 2000, 287 (5460) :1989-1992