Invertible amphiphilic homopolymers

被引：123

作者：

Basu, S ^{[1
]}

Vutukuri, DR ^{[1
]}

Shyamroy, S ^{[1
]}

Sandanaraj, BS ^{[1
]}

Thayumanavan, S ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 32期

关键词：

D O I：

10.1021/ja047816a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stimuli-responsive polymers and assemblies are viable candidates for the so-called "smart" materials. In this communication, we report a new class of amphiphilic homopolymers that forms micelle-like structures in polar solvents and inverted micelle-like structures in apolar solvents. We demonstrate that these superstructures are the result of the changes in the molecular-level conformations in the monomer. Copyright © 2004 American Chemical Society.

引用

收藏

页码：9890 / 9891

页数：2

相关论文

共 19 条

[1] Switching the inside and the outside of aggregates of water-soluble block copolymers with double thermoresponsivity [J].

Arotçaréna, M ;

Heise, B ;

Ishaya, S ;

Laschewsky, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (14) :3787-3793

[2] Levels of structure formation in aqueous solutions of anisotropic association colloids consisting of rodlike polyelectrolytes [J].

Bockstaller, M ;

Köhler, W ;

Wegner, G ;

Vlassopoulos, D ;

Fytas, G .

MACROMOLECULES, 2001, 34 (18) :6359-6366

[3] Aqueous self-assembly of unsymmetric peptide bolaamphiphiles into nanofibers with hydrophilic cores and surfaces [J].

Claussen, RC ;

Rabatic, BM ;

Stupp, SI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (42) :12680-12681

[4]

CONRNELISSEN JJL, 1998, SCIENCE, V280, P1427

[5] Polymer vesicles [J].

Discher, DE ;

Eisenberg, A .

SCIENCE, 2002, 297 (5583) :967-973

[6] Y-shaped amphiphilic brushes with switchable micellar surface structures [J].

Julthongpiput, D ;

Lin, YH ;

Teng, J ;

Zubarev, ER ;

Tsukruk, VV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (51) :15912-15921

[7] Preparation and pH triggered inversion of vesicles from poly(acrylic acid)-block-polystyrene-block-poly(4-vinyl pyridine) [J].

Liu, FT ;

Eisenberg, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (49) :15059-15064

[8]

Liu SY, 2002, ANGEW CHEM INT EDIT, V41, P1413, DOI 10.1002/1521-3773(20020415)41:8<1413::AID-ANIE1413>3.0.CO

[9]

2-K

[10] Chemically induced supramolecular reorganization of triblock copolymer assemblies: Trapping of intermediate states via a shell-crosslinking methodology [J].

Ma, QG ;

Remsen, EE ;

Clark, CG ;

Kowalewski, T ;

Wooley, KL .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :5058-5063