Correlation between i.r. spectra and thermal decomposition of cobalt(II), nickel(II), copper(II) and mercury(II) complexes with piperidinedithiocarbamate and pyrrolidinedithiocarbamate

被引:30
作者
Cavalheiro, ÉTG
Ionashiro, M
Marino, G
Breviglieri, ST
Chierice, GO
机构
[1] UFSCar, Dept Quim, BR-13565905 Sao Paulo, Brazil
[2] UNESP, Inst Quim, BR-14800900 Sao Paulo, Brazil
[3] USP, Inst Quim S Carlos, BR-13560970 Sao Paulo, Brazil
关键词
D O I
10.1023/A:1007044130951
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The thermal decomposition of pyrrolidinedithiocarbamate and piperidinedithiocarbamate complexes of Co-II, Ni-II, Cu-II and Hg-II have been studied by thermogravimetry and differential scanning calorimetry. The decomposition intermediates and final products were identified by their X-ray diffraction patterns. The i.r. spectra are discussed in terms of the thermal decomposition pathways.
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页码:69 / 72
页数:4
相关论文
共 17 条
[1]   The effect of the aminic substituent on the thermal decomposition of cyclic dithiocarbamates [J].
Cavalheiro, ETG ;
Ionashiro, M ;
Marino, G ;
Breviglieri, ST ;
Chierice, GO .
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 1999, 10 (01) :65-75
[2]   ISOTOPIC INFRARED STUDY OF SOME NICKEL(II) AND COPPER(II) COMPLEXES CONTAINING HETEROCYCLIC DITHIOCARBAMATE LIGANDS [J].
DESSEYN, HO ;
FABRETTI, AC ;
FORGHIERI, F ;
PRETI, C .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1985, 41 (09) :1105-1108
[3]   SPECTROSCOPIC, MAGNETIC AND THERMOGRAVIMETRIC STUDIES OF PIPERAZINE-BIS-(DITHIOCARBAMATE) COMPLEXES [J].
FABRETTI, AC ;
FORGHIERI, F ;
GIUSTI, A ;
PRETI, C ;
TOSI, G .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1984, 40 (04) :343-346
[4]   BEHAVIOR OF METAL TETRAMETHYLENEDITHIOCARBAMATES IN GRAPHITE-TUBE FURNACE FOR ATOMIC-ABSORPTION SPECTROMETRY [J].
GOMISCEK, S ;
LENGAR, Z ;
CERNETIC, J ;
HUDNIK, V .
ANALYTICA CHIMICA ACTA, 1974, 73 (01) :97-106
[5]   X-RAY-DIFFRACTION STUDY OF THERMAL-DECOMPOSITION OF METAL TETRAMETHYLENEDITHIOCARBAMATES [J].
GOMISCEK, S ;
GOLIC, L ;
LENGAR, Z .
ANALYTICA CHIMICA ACTA, 1975, 79 (OCT) :296-301
[6]   PROBLEM OF BAND SHIFTS IN IR-SPECTRA OF DIETHYLDITHIOCARBAMIDATES AND TETRAMETHYLENEDITHIOCARBAMIDATES [J].
KELLNER, R .
ANALYTICA CHIMICA ACTA, 1973, 63 (02) :277-284
[7]   PROBLEM OF BAND SHIFT IN IR-SPECTRA OF DIALKYLDITHIOCARBAMIDATES .3. PYRROLEDITHIOCARBOXYLATES - RANGE OF 4000-300 1/CM [J].
KELLNER, R ;
PROKOPOW.P ;
MALISSA, H .
ANALYTICA CHIMICA ACTA, 1974, 68 (02) :401-406
[8]  
KELLNER R, 1975, MIKROCHIM ACTA, V2, P24
[9]  
Magee R.J., 1985, Rev. Anal. Chem, V8, P5, DOI [10.1515/revac.1985.8.1-2.5, DOI 10.1515/REVAC.1985.8.1-2.5]
[10]   UBER DIE LOSLICHKEIT EINIGER PYRROLIDINKARBAMINATE IN ORGANISCHEN LOSUNGSMITTELN [J].
MALISSA, H ;
GOMISCEK, S .
ANALYTICA CHIMICA ACTA, 1962, 27 (04) :402-&