Organometallic-type reactions in aqueous media mediated by indium: Application to the synthesis of carbohydrates

被引：125

作者：

Chan, TH

Isaac, MB

机构：

[1] Department of Chemistry, McGill University, Montreal

来源：

PURE AND APPLIED CHEMISTRY | 1996年 / 68卷 / 04期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1351/pac199668040919

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Indium-mediated coupling reaction of carbonyl compounds with allylic halides in aqueous media to give homoallylic alcohols was studied in details regarding its regio- and stereoselectivity. A mechanism accounting for the observations has been proposed. The, reaction has been applied to the syntheses of a number of sialic acids including KDN and neu5NAc.

引用

页码：919 / 924

页数：6

共 15 条

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