Nonlinear optical materials derived from biopolymer (DNA)-surfactant-Azo dye complex

被引:32
作者
Zhang, GJ [1 ]
Takahashi, H [1 ]
Wang, LL [1 ]
Yoshida, J [1 ]
Kobayashi, S [1 ]
Horinouchi, S [1 ]
Ogata, N [1 ]
机构
[1] Chitose Inst Sci & Technol, Chitose, Hokkaido 0668655, Japan
来源
APOC 2002: ASIA-PACIFIC OPTICAL AND WIRELESS COMMUNICATIONS; MATERIALS AND DEVICES FOR OPTICAL AND WIRELESS COMMUNICATIONS | 2002年 / 4905卷
关键词
disperse red-13; DNA-surfactant complex film; intercalation; circular dichroism; THG;
D O I
10.1117/12.481027
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
This paper reports on optical and optoelectronic properties of DNA-surfactant complex films which were intercalated with a NLO dye, Disperse Red 13(DR-13). Circular dichroism (CD) analysis indicated that the orientation of the azo dye, DR-13 doped in DNA-surfactant complex film was achieved by inserting the dye molecules into the nano-size space between base pairs of DNA. The Disperse Red 13-doped DNA thin film displayed higher THG than that of CS2 about two orders. On the other hand, SHG signal-could not be observed even in the presence of anisotropic ordering of the molecular chromospheres on template of the double helix of DNA, perhaps because of absorption of the dye for SHG light.
引用
收藏
页码:375 / 380
页数:6
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