Recognition and encapsulation of an electroactive guest within a dynamically folded polymer

被引：35

作者：

Galow, TH

Ilhan, F

Cooke, G

Rotello, VM ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

[2] Northumbria Univ, Dept Chem & Life Sci, Newcastle Upon Tyne NE1 8ST, Tyne & Wear, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2000年 / 122卷 / 15期

关键词：

D O I：

10.1021/ja993735g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diaminotriazine-functionalized polymer 1 folds in nonpolar media into unimolecular "micelles", in which the diaminotriazine units are inwardly directed to form a polar pocket analogous to the active sites found in proteins. To explore the possibility of site isolation within this pocket we synthesized the redox active guest 6-ferrocenyluracil 2. Encapsulation of guest 2 by polymer 1 was established by NMR studies; functional site isolation was demonstrated through cyclic voltammetry studies.

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页码：3595 / 3598

页数：4

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