A selected ion flow tube study of the reactions of small CmHn+ ions with O atoms

被引：26

作者：

Scott, GBI ^{[1
]}

Milligan, DB ^{[1
]}

Fairley, DA ^{[1
]}

Freeman, CG ^{[1
]}

McEwan, MJ ^{[1
]}

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

JOURNAL OF CHEMICAL PHYSICS | 2000年 / 112卷 / 11期

关键词：

D O I：

10.1063/1.481050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions of thirteen CmHn+ ions (m less than or equal to 6) with atomic and molecular oxygen and nitric oxide have been measured using a selected ion flow tube operating at room temperature. Rate coefficients and product distributions are reported for each reaction. Most of the hydrocarbon ions studied exhibit relatively rapid reactions with O atoms and proceed at substantial fractions of the collision rate. All O atom reactions showed multiple product channels and the formation of a -C-O bond, either in the ion product or the neutral product of reaction. (C) 2000 American Institute of Physics. [S0021-9606(00)00811-4].

引用

页码：4959 / 4965

页数：7

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