Tuning interaction in dinuclear ruthenium complexes: HOMO versus LUMO mediated superexchange through azole and azine bridges

被引：98

作者：

Browne, Wesley R.

Hage, Ronald

Vos, Johannes G. ^{[1
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Natl Ctr Sensor Res, Dublin 9, Ireland

[2] Univ Groningen, NL-9700 AB Groningen, Netherlands

[3] Unilever Res Labs, NL-3133 AT Vlaardingen, Netherlands

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 13-14期

关键词：

mixed valence; spectroelectrochemistry; ruthenium; azine; azole;

D O I：

10.1016/j.ccr.2005.12.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this review the interaction between metal centers in dinuclear complexes based on azole and azine containing bridging ligands is reviewed. The focus of the review is on the manner in which the interaction pathway can be manipulated by variations in the nature of both the direct bridging unit and the peripheral substituents. Ruthenium polypyridyl type complexes will form the basis of this overview with particular attention paid to the electrochemical and spectroelectrochemical investigation of mixed valence compounds. (c) 2005 Elsevier B.V. All rights reserved.

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页码：1653 / 1668

页数：16

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