Magnetic properties of the low-dimensional cuprate Na5RbCu4(AsO4)4Cl2 -: art. no. 052403

被引:20
作者
Clayhold, JA [1 ]
Ulutagay-Kartin, M
Hwu, SJ
Koo, HJ
Whangbo, MH
Voigt, A
Eaiprasertsak, K
机构
[1] Clemson Univ, Dept Phys & Astron, Kinard Lab, Clemson, SC 29634 USA
[2] Clemson Univ, Dept Chem, Clemson, SC 29634 USA
[3] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA
[4] Univ Georgia, Dept Phys & Astron, Ctr Simulat Phys, Athens, GA 30602 USA
[5] Clemson Univ, Dept Mat Sci, Clemson, SC 29634 USA
关键词
D O I
10.1103/PhysRevB.66.052403
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The magnetic properties of Na5RbCu4(AsO4)(4)Cl-2 are reported. The material has a layered structure comprised of square Cu4O4 tetramers. The Cu ions are divalent and the system behaves as a low-dimensional S=1/2 antiferromagnet. Spin exchange in Na5RbCu4(AsO4)(4)Cl-2 appears to be quasi-two-dimensional and nonfrustrated. Measurements of the bulk magnetic susceptibility and heat capacity are consistent with low-dimensional magnetism. The compound has an interesting, low-entropy, magnetic transition at T=17 K.
引用
收藏
页码:524031 / 524034
页数:4
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