Pore structure development in activated carbon honeycombs

被引:53
作者
Gadkaree, KP
Jaroniec, M
机构
[1] Corning Inc, Corning, NY 14830 USA
[2] Kent State Univ, Dept Chem, Kent, OH 44242 USA
关键词
activated carbon; resins; adsorption; microporosity;
D O I
10.1016/S0008-6223(99)00204-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work describes the development of porosity in activated carbon honeycomb structures. The honeycombs were fabricated from a combination of synthetic precursors, i.e., phenolic resins, along with several organic and inorganic additives, which allowed their extrusion at room temperature as well as subsequent carbonization and activation. The pore size and pore volume of these structures depend on the level of activation and the precursor composition. It was found that essentially micropores are formed when pure phenolic resin is used. The introduction of metal catalysts in the resin precursor was evaluated as a means to change the pore structure of the final product. The presence of the metal catalyst changes the final pore structure significantly, as evidenced by the formation of a large volume of meso- and macropores, particularly at high activation levels. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:983 / 993
页数:11
相关论文
共 18 条
[1]  
[Anonymous], 1992, CONSTITUTION SLOVAK
[2]  
Bansal C. R., 1988, ACTIVE CARBON
[3]   Steam-carbon gasification catalyzed by calcium: Assessment of the porous structure of active carbons from plum stones and synthetic active carbons [J].
Dabrowski, A ;
Fekner, Z ;
Leboda, R ;
Goworek, J .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 1997, 3 (03) :233-242
[4]   Carbon honeycomb structures for adsorption applications [J].
Gadkaree, KP .
CARBON, 1998, 36 (7-8) :981-989
[5]  
GADKAREE KP, 1998, Patent No. 5820967
[6]  
Jankowska H., 1991, Active Carbon
[7]  
Jaroniec M, 1997, STUD SURF SCI CATAL, V104, P715
[8]   Physicochemical foundations for characterization of adsorbents by using high-resolution comparative plots [J].
Jaroniec, M ;
Kaneko, K .
LANGMUIR, 1997, 13 (24) :6589-6596
[9]  
JARONIEC M, 1995, ACCESS NANOPOROUS MA, P255
[10]  
JARONIEC M, 1988, PHYSICAL ADSORPTION