Rational design of a solid acid catalyst for the conversion of methanol to light alkenes: Synthesis, structure and performance of DAF-4

被引：34

作者：

Barrett, PA

Jones, RH

Thomas, JM

Sankar, G

Shannon, IJ

Catlow, CRA

机构：

[1] UCL ROYAL INST GREAT BRITAIN, DAVY FARADAY RES LAB, LONDON W1X 4BS, ENGLAND

[2] UNIV KEELE, DEPT CHEM, KEELE ST5 5BG, STAFFS, ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 17期

关键词：

D O I：

10.1039/cc9960002001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By careful choice of the appropriate organic template, new shape-selective solid acid catalysts-framework-substituted microporous aluminium phosphates (AlPO4) that are structurally analogous to the mineral levyne-are designed, synthesised and characterised; they convert methanol preferentially to ethene and propene.

引用

收藏

页码：2001 / 2002

页数：2

相关论文

共 25 条

[1]

AKPORIAYE DE, 1996, J CHEM SOC CHEM COMM, P601

[2] INTRACRYSTALLINE CHANNELS IN LEVYNITE AND SOME RELATED ZEOLITES [J].

BARRER, RM ;

KERR, IS .

TRANSACTIONS OF THE FARADAY SOCIETY, 1959, 55 (11) :1915-&

[3] INVESTIGATION OF THE STRUCTURAL STABILITY OF COBALT-CONTAINING ALPO-44 MICROPOROUS MATERIALS [J].

BARRETT, PA ;

SANKAR, G ;

CATLOW, CRA ;

THOMAS, JM .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1995, 56 (10) :1395-1405

[4] X-ray absorption spectroscopic study of Bronsted, Lewis, and redox centers in cobalt-substituted aluminum phosphate catalysts [J].

Barrett, PA ;

Sankar, G ;

Catlow, CRA ;

Thomas, JM .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (21) :8977-8985

[5] THE PORE-SIZE MODIFICATION OF A LAYERED ALUMINOPHOSPHATE [AL3P4O16C9H24N3] BY RATIONAL SELECTION OF THE INTERCALATED TEMPLATE CATION [J].

BARRETT, PA ;

JONES, RH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) :1979-1981

[6]

BARRETT PB, UNPUB

[7]

Binsted N., 1991, EXCURV92

[8] MAPO-18 (M-MG,ZN,CO) - A NEW FAMILY OF CATALYSTS FOR THE CONVERSION OF METHANOL TO LIGHT OLEFINS [J].

CHEN, JS ;

THOMAS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (05) :603-604

[9] COBALT-SUBSTITUTED ALUMINOPHOSPHATE MOLECULAR-SIEVES - X-RAY ABSORPTION, INFRARED SPECTROSCOPIC, AND CATALYTIC STUDIES [J].

CHEN, JS ;

SANKAR, G ;

THOMAS, JM ;

XU, RR ;

GREAVES, GN ;

WALLER, D .

CHEMISTRY OF MATERIALS, 1992, 4 (06) :1373-1379

[10] INORGANIC SOLID ACIDS AND THEIR USE IN ACID-CATALYZED HYDROCARBON REACTIONS [J].

CORMA, A .

CHEMICAL REVIEWS, 1995, 95 (03) :559-614